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The ATX power supply is quite different from an AT.
Besides the AT not supplying the correct voltages, there is a 5 volt circuit in all ATX supplies that is never off...unless there is a master switch between the PSU and the wall socket..or the computer is disconnected from the power source.
This 5 volt circuit is what turns on the main power supply..it like two power supplies in one housing.
An ATX supply is not designed to be turned on/off with a switch...and would require considerable re-engineering and mods to make it work.
The 3.3 volts used in an ATA supply could possibly be derived from the 5 volt rail in an AT supply, but it would not be regulated..and would create problems in the computer system because of varying voltages (non regulated output).
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