Well, you could turn that computer into a internet router/firewall with two network cards!
IPCop will take over the whole PC, but use the two network cards to keep your internal LAN safe from the nasty world wide wicked.
Depending on what kinda OS you run, you could also do load balancing with 2 NIC's, but it's not really much help for anything except fail-safe stuff IMO.
Might be kinda neat to try it and see if you can get the two NICs sharing a connection. Just for laughs, anyhow.
Cheers
Mick