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I don't think you are going to notice a difference in the drives per se. If it were me and it was feesable to do, I would use the slightly faster ATA100 drive as my main drive, and the older drive as my back up on the same ATA bus.
Currently I have a 40 gig ATA133 as my main drive and a 15gig ATA100 as my back up/file storage. I won't build another computer any other way, even if I just have a small 3 gig drive as a back up. It gives me a safe place to put things until I burn them onto CD. Even if the main drive dies, I've still got my important data.
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do it right, do it yourself. If that doesn't work, prepare to pay for your mistakes.
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