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Well, in order to get the exchange 5.5 database transfered, you will have to have the Information Store offline. So you could use that time to disable the old nic and then transfer the info.
Can your old email box "see" the new mail box right now? Because if they are on different subnets then you can leave the slow NIC on the 192.168.x.x, and configure the fast NIC on the 10.
It has been a long time since i had setup two nics in a win2k server to talk to two different subnets, so i am sorry i cant give you more info off the top of my head.
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