you mean a ring topology ? Yes they can but to be honest you won't really notice much performance diffrence as its highly unlikely that you'll ever out grow the 100mbit as a IDE HDD can't utilise the full 100mbit connection. If you tell me exactly what your trying to do i'll give you the best way to set it up if you wish

i will need to know exactly what the network will be doing i.e gaming or file sharing and how big are the files, and what connection topology you will be using i.e peer to peer or client server