According to the manual for your board, the AGP Aperture Size setting is located under the "Advanced Chipset Features" menu in the BIOS. See my enclosed screen shot.
You can set it to 1/2 your SYSTEM RAM and you might notice increase performance, you might not.
Your best step right now would be to run a benchmark utility like 3DMark and see what kinda score you get. After that, change your AGP Aperture Size up to 128, benchmakr again, change it to 256, benchmark. See which one gives you the best score and change it to that setting.
You can find the latest 3DMark03
here