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I had this same problem. Does your machine blue-screen and then reboot when copying large files from one drive to the other? I had real problem with. Turned out that it was the VIA drivers I was using were causing the problem (they came on the driver disk with the motherboard). The one difference I see between your Device Manager layout and mine is that I'm using a Promise ATA controller card and I had two other devices listed as as SCSI controllers. After I removed them, the VIA UDMA drivers, and restarted everything was okay. XP re-installed the correct IDE controller drivers and everything worked fine after that.
Oh, and I'm using a DFI mobo with the AMD 761 chipset. Oddly enough, we're both using the same models of hard drives (both of them).
HTH's
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