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Well, the only thing you could feasibly do is try to figure out how much the sound and video are out of sync after a certain amount of time into the movie. Then you will able to calculate approximately what the frame rate of the audio is vs. the frame rate of the video. Normally this out of sync is due to a careless setting or not enough processing power to encode the video from a live stream, either the audio or video seems to fall behind.
Ne ways, now that you know what the difference in frame rate is, you would be able to adjust the audio frame rate to make it inline with the video using a program such as virtual dub.
As you can see this is a fairly involved task and all in all, not worth the effort
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