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the short answer is no, you would not notice a performance difference in windows.
however, if you use any programs that utilize large ammounts of RAM, or if you regularly multitask with programs that use a good ammount of RAM, you will notice some performance improvements.
if you play any of the latest 3D games, you will definitely notice a performance improvement.
there are a number of htings to consider as to why you might need more RAM, but you can not have too much. if you feel like that is a cost effective upgrade compared to your processor, motherboard, upgrading your optical drive, etc, then by all means go for it. if you're looking for a specific area of performance gain, consider the factors (what aplications you want the performance boost in) and then weigh what gains will be made from which upgrade and decide that way.
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