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Manually by log in with the new domain account to create the profile.
Then logoff the user and logon as the administrator account.
Right click My Computer, Properties, User Profiles, click on the existing domain account and click "Copy To...". Browse to the new domain profile folder (c:\documents and settings\(new domain profile)) and click OK. All settings, desktop icons, favorites, and files in the My Documents folder will be moved to the new profile folder.
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