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Yes.
Google on unused pairs cat5 and you will find many sources that verify there are two unused pairs with the standard I referenced.
You will also find references that say it is both "okay" and also a "bad idea" to use the spare pairs for an analog phone connection.
If this was the planning stages, or even a commercial application, I would suggest you didn't do it.
In the situation where it is at home (ie: not critical) and the wire is already there, then try. It will work and performance degradation will not even be noticed.
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