Well they should work, the difference is ecc is error correcting codes, having two sticks that atleast have that is for the best, but keeping them exactly the same especially if the system requires ecc, registered modules, but the ideal situation is to use two identical sticks.
For more information of parts of the memory sticks you should watch this presentation even tho it is for ddr, the ecc and register or buffered part still applys.
http://www.corsairmemory.com/corsair...707/index.html
If not skip through to those parts